This study presents dinuclear alkenylruthenium complexes featuring π-extended trans,trans-distyrylbenzene or 1,4-(2-phenylethynyl)benzene linkers, analogous to oligophenylvinylene and oligophenylethynylene oligomers, as well as the macrocyclic analogue. Characterized by NMR spectroscopy and high-resolution ESI-MS, the compounds undergo detailed examination of their electrochemical and spectroscopic properties. The study explores the efficacy of intramolecular through-bond electron transfer in…